HuagongsheHuagongshe Chemistry Print Report · For research reference only
Tributylstannane → 2-Propenoic acid, 2-[(tributylstannyl)methyl]-, ethyl ester
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Tributylstannane | HCID 5948 | — |
| Reactant | Azobisisobutyronitrile | HCID 6547 | — |
| Reactant | 89295-32-9 | HCID 361163 | — |
| Solvent | Benzene | HCID 241 | — |
| Product | 2-Propenoic acid, 2-[(tributylstannyl)methyl]-, ethyl ester | HCID 11014935 | — |
Reaction Steps
(Formula I, X=Sn, R1=—COOCH2CH3, R2=n-butyl, n=3). This compound was prepared from ethyl α-(benzenesulphonylmethyl)acrylate, n-Bu3SnH and AIBN in benzene at 80° C. for 1.5 h according to the procedure described in Journal of the Chemical Society, Chemical Communications, 1986, 1339-1340. 1H NMR (CDCl3) δ 0.85-1.65 (30H, m, 3×CH2CH2CH2CH2CH3, OCH2CH3), 2.00 (2H, s, allylic CH2Sn), 4.15 (2H, q, OCH2CH3, J 7.5 Hz), 5.25 (1H, s, olefinic proton), 5.75 (1H, s, olefinic proton).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06197905B1 |
| Source dataset | uspto-grants-2001_03 |
| ORD ID | ord-cc140e98d4c145d1ba915fbc7f6a82d6 |
| Source note | uspto-grants-2001_03 |