Aniline → HCID 178426071, compound

Participants

Reaction Conditions

Reaction Steps

Sodium hydride (containing mineral oil; the content of sodium hydride: 60 wt. %) (0.60 g) was suspended in tetrahydrofuran (6.91 g), and then aniline (0.047 g) was dropwise added to the suspension at 25° C. After heating to 50° C., the suspension was stirred for 10 minutes. Thereafter, tetramethylcyclopentadiene (1.22 g) was dropwise added to the suspension while maintaining the suspension at 50° C., followed by stirring for one hour. Thus, tetramethylcyclopentadienylsodium was obtained. After cooling the above solution to 20° C., the solution of (2-allyloxy-3-tert.-butyl-5-methylphenyl)chlorodimethylsilane (3.86 g; purity: 73%; pure compound: 2.82 g) in toluene was dropwise added to the above solution, followed by stirring for 2 hours.

Provenance & Evidence