HuagongsheHuagongshe Chemistry Print Report · For research reference only
N-bromobutanimide → Methyl 5-(bromomethyl)-2-methoxybenzoate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | N-bromobutanimide | HCID 67184 | — |
| Reactant | Methyl 2-methoxy-5-methylbenzoate | HCID 10241396 | — |
| Solvent | Benzene | HCID 241 | — |
| Product | Methyl 5-(bromomethyl)-2-methoxybenzoate | HCID 19744340 | — |
Reaction Steps
A mixture of 2-methoxy-5-methylbenzoic acid methyl ester (J.Chem.Soc.Perkin Trans.1, 1994, 1125) (1.47 g) and N-bromosuccinimide (1.45 g) in benzene (15 ml) was irradiated under a 500 W halogen lamp for 3 hours. The solvent was evaporated and the residue triturated with diethyl ether. The succinimide was filtered off and the filtrate evaporated.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06200981B1 |
| Source dataset | uspto-grants-2001_03 |
| ORD ID | ord-cc5a220a1f5644198b9e4917cab8fd4f |
| Source note | uspto-grants-2001_03 |