HRID1532595

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：C[N+]1(CCN=C=NC2CCCCC2)CCOCC1.Cc1ccc(S(=O)(=O)[O-])cc1

HCID17220

4-(2-{[(Cyclohexylimino)methylidene]amino}ethyl)-4-methylmorpholin-4-ium 4-methylbenzene-1-sulfonate

C21H33N3O4S

HCID92463

Cyclopropyl isothiocyanate

C4H5NS

HCID100529

3,4,5-Trichlorobenzene-1,2-diamine

C6H5Cl3N2

PRODUCTS

生成物

HCID22995411

未命名化合物

收率 83.3%

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID1049

Pyridine

C5H5N

PROCEDURE

实验过程

3,4,5-Trichloro-1,2-phenylenediamine (3.02 g, 14.28 mmol), cyclopropyl isothiocyanate (1.53 g, 15.42 mmol), 1-cyclohexyl-3-(2-morpholinoethyl)carbodiimide metho-p-toluenesulfonate (8.24 g, 19.45 mmol) and pyridine (55 mL) were used according to general procedure I. The product was recrystallized from 1,4-dioxane to afford 3.29 g (83%) of a white solid. MS (CI): m/z 274. Anal. Calcd for C10H8Cl3N3-(0.6 C4H8O2): C, 45.21; H, 3.92; N, 12.76. Found: C, 45.37; H, 3.91; N, 12.76.

WORKUP

后处理

customThe product was recrystallized from 1,4-dioxane