3-Chlorocarbonyl-propionic acid 3,7-dimethyl-oct-6-enylester → Succinic acid 3,7-dimethyl-oct-6-enyl ester 2,6,10-trimethyl-undeca-1,9-dienyl ester

HRID 1533699Notes

Reaction equation

HRID 1533699 reaction equation
[CH3:1][C:2]([CH2:22][CH2:23][CH2:24][CH:25]([CH3:32])[CH2:26][CH2:27][CH:28]=[C:29]([CH3:31])[CH3:30])=[CH:3][O:4][C:5](=[O:21])[CH2:6][CH2:7][C:8]([O:10][CH2:11][CH2:12][CH:13]([CH3:20])[CH2:14][CH:15]=[CH:16][CH:17]([CH3:19])[CH3:18])=[O:9].CC(CCCC(C)CCC=C(C)C)=COC(=O)C.CC(CCC=C(C)C)CCOC(=O)CCC(Cl)=O.CC(C)([O-])C.[K+]>>[CH3:1][C:2]([CH2:22][CH2:23][CH2:24][CH:25]([CH3:32])[CH2:26][CH2:27][CH:28]=[C:29]([CH3:30])[CH3:31])=[CH:3][O:4][C:5](=[O:21])[CH2:6][CH2:7][C:8]([O:10][CH2:11][CH2:12][CH:13]([CH3:20])[CH2:14][CH2:15][CH:16]=[C:17]([CH3:18])[CH3:19])=[O:9]

Participants

5

Reactant 4

HCID 153907233-Chlorocarbonyl-propionic acid 3,7-dimethyl-oct-6-enylesterHCID 23665647Potassium tert-butoxideHCID 53979183Acetic acid 2,6,10-trimethyl-undeca-1,9-dienyl esterHCID 86756562Succinic acid 3,7-dimethyl-oct-5-enyl ester 2,6,10-trimethyl-undeca-1,9-dienyl ester

Product 1

HCID 86756561Succinic acid 3,7-dimethyl-oct-6-enyl ester 2,6,10-trimethyl-undeca-1,9-dienyl ester

Procedure

According to the same procedure, succinic acid 3,7-dimethyl-oct-5-enyl ester 2,6,10-trimethyl-undeca-1,9-dienyl ester was prepared from acetic acid 2,6,10-trimethyl-undeca-1,9-dienyl ester, 3-chlorocarbonyl-propionic acid 3,7-dimethyl-oct-6-enyl ester and potassium tert-butoxide.

Sources & evidence

ORD record
ord-03c81c3c08484bfc800175fba7a4dd34
Source dataset
uspto-grants-2001_03
Patent number
US06207857B1

Reaction notes

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