HuagongsheHuagongshe Chemistry Print Report · For research reference only
Phenol → 3-(1-Phenoxytridecyl)-5-trimethylsilylfuran
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Phenol | HCID 996 | — |
| Reactant | 3-(1-Chlorotridecyl)-5-trimethylsilylfuran | HCID 15037076 | — |
| Reactant | Potassium methoxide | HCID 23664618 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | 3-(1-Phenoxytridecyl)-5-trimethylsilylfuran | HCID 19909508 | — |
Reaction Steps
A mixture of 3-(1-chlorotridecyl)-5-trimethylsilylfuran, phenol and potassium methoxide in tetrahydrofuran is stirred at room temperature to give 3-(1-phenoxytridecyl)-5-trimethylsilylfuran. A mixture of this intermediate and Rose Bengal in tetrahydrofuran is exposed to oxygen by the procedure of Example 1 to give 4-(1-phenoxytridecyl)-5-hydroxy-2(5H)-furanone.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05089485 |
| Source dataset | uspto-grants-1992_02 |
| ORD ID | ord-20a2e5caba7744579d087991b4cbb4a5 |
| Source note | uspto-grants-1992_02 |