Potassium peroxymonosulphate → HCID 19909521, compound

HRID 1534346Notes

Reaction equation

[CH3:1][S:2]([CH:4]([C:17]1[CH:21]=[C:20]([Si:22]([CH3:25])([CH3:24])[CH3:23])[O:19][CH:18]=1)[CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16])=[O:3].S([O-])(O[O-])(=O)=[O:27].[K+].[K+]>>[CH3:1][S:2]([CH:4]([C:17]1[CH:21]=[C:20]([Si:22]([CH3:23])([CH3:24])[CH3:25])[O:19][CH:18]=1)[CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16])(=[O:27])=[O:3]

Participants

Reactant 2

HCID 10313463Potassium peroxymonosulphate

HCID 19909506HCID 19909506, compound

Product 1

HCID 19909521HCID 19909521, compound

Procedure

3-(1-methylsulfinyltridecyl)-5-trimethylsilylfuran is oxidized using potassium peroxymonosulfate to give 3-(1-methylsulfonyltridecyl)-5-trimethylsilylfuran. Oxidizing with singlet oxygen by the procedure of Example 1 gives 4-(1-methylsulfonyltridecyl)-5-hydroxy-2(5H)-furanone.

Sources & evidence

ORD record: ord-41cbb7df9bdf40309e81ab758400275b
Source dataset: uspto-grants-1992_02
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05089485

Reaction notes

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