Methyl Anthranilate → HCID 178450489, compound

HRID 1534361Notes

Reaction equation

HRID 1534361 reaction equation
[C:1]([C:6](=[CH:12]OCC)[C:7]([O:9][CH2:10][CH3:11])=[O:8])(=[O:5])[CH2:2][CH2:3][CH3:4].[C:16]([O:25][CH3:26])(=[O:24])[C:17]1[C:18](=[CH:20][CH:21]=[CH:22][CH:23]=1)[NH2:19]>>[C:1]([C:6](=[CH:12][NH:19][C:18]1[CH:20]=[CH:21][CH:22]=[CH:23][C:17]=1[C:16]([O:25][CH3:26])=[O:24])[C:7]([O:9][CH2:10][CH3:11])=[O:8])(=[O:5])[CH2:2][CH2:3][CH3:4]

Participants

3

Reactant 2

HCID 8635Methyl AnthranilateHCID 3359484Ethyl 2-butyryl-3-ethoxyacrylate

Product 1

HCID 178450489HCID 178450489, compound

Procedure

A mixture of ethyl 2-butyryl-3-ethoxyacrylate (21.4 g, 0.1 mol) and methyl anthranilate (12.9, ml, 0.1 mol) was heated to boiling for 20 minutes, then cooled and triturated with petroleum ether to obtain ethyl 2-butyryl3-(2-carbomethoxyphenylamino)acrylate as a mixture of E/Z isomers (18.0 g, 56%).

Workup

  1. temperatureml, 0.1 mol) was heated
  2. temperaturecooled
  3. customtriturated with petroleum ether

Sources & evidence

ORD record
ord-8a9801a64fb4406b9508565b1a05dd55
Source dataset
uspto-grants-1992_02
Patent number
US05089498

Reaction notes

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