HuagongsheHuagongshe Chemistry Print Report · For research reference only
3,3-Dichloro-6,6-dimethylazepan-2-one → 3-Chloro-6,6-dimethylazepan-2-one
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 3,3-Dichloro-6,6-dimethylazepan-2-one | HCID 15165799 | — |
| Reactant | HCID 178418361 | HCID 178418361 | — |
| Catalyst | Palladium | HCID 23938 | — |
| Solvent | Acetic Acid | HCID 176 | — |
| Product | 3-Chloro-6,6-dimethylazepan-2-one | HCID 15165800 | 99.5% |
Reaction Steps
3.0 g (14.3 mmoles) of 3,3-dichloro-6,6-dimethyl-2-oxoperhydroazepine were dissolved in 300 ml of glacial acetic acid and shaked at 40 psi of hydrogen with 1.9 g of 10% Pd/C. When the theoretical amount of hydrogen was consumed the catalyst was filtered off and the filtrate evaporated in vacuo to yield 2.5 g of the title compound.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05089507 |
| Source dataset | uspto-grants-1992_02 |
| ORD ID | ord-451060bddff9422395027ce4a343cc5f |
| Source note | uspto-grants-1992_02 |