HCID 12640713, compound → HCID 178440526, compound

HRID 1534672Notes

Reaction equation

HRID 1534672 reaction equation
[Li][P:2]([C:7]([CH3:10])([CH3:9])[CH3:8])[C:3]([CH3:6])([CH3:5])[CH3:4].[Li][As](C(C)(C)C)C(C)(C)C.[Al:21](Cl)([C:26]([CH3:29])([CH3:28])[CH3:27])[C:22]([CH3:25])([CH3:24])[CH3:23]>>[Al:21]([P:2]([C:7]([CH3:10])([CH3:9])[CH3:8])[C:3]([CH3:6])([CH3:5])[CH3:4])([C:26]([CH3:29])([CH3:28])[CH3:27])[C:22]([CH3:25])([CH3:24])[CH3:23]

Participants

4

Reactant 3

HCID 12640713HCID 12640713, compoundHCID 14494088HCID 14494088, compoundHCID 178506961HCID 178506961, compound

Product 1

HCID 178440526HCID 178440526, compound

Procedure

The process of Example 1 was substantially followed except LiP(t-Bu)2 was substituted for LiAs(t-Bu)2 in the same molar proportions with respect to (t-Bu)2AlCl which was substituted for (t-Bu)2GaCl. The monomeric phosphinoalane, (t-Bu)2AlP(t-Bu)2, was produced. See NMR Table 1.

Sources & evidence

ORD record
ord-82a31236193844e482e9cf04b70d1d89
Source dataset
uspto-grants-1992_02
Patent number
US05089643

Reaction notes

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