Dimethyl Sulfoxide → Dibenzyl 5-nitro-2-pyridylmalonate

HRID 1550724Notes

Reaction equation

HRID 1550724 reaction equation
[C:7]([CH2:8][C:9](=[O:10])[O:11][CH2:12][c:13]1[cH:14][cH:15][cH:16][cH:17][cH:18]1)(=[O:19])[O:20][CH2:21][c:22]1[cH:23][cH:24][cH:25][cH:26][cH:27]1.[CH3:1][C:2]([CH3:3])([O-:4])[CH3:5].[CH3:38][S:39]([CH3:40])=[O:41].[Cl:28][c:29]1[n:30][cH:31][c:32]([N+:35](=[O:36])[O-:37])[cH:33][cH:34]1.[K+:6]>>[C:7]([CH:8]([C:9](=[O:10])[O:11][CH2:12][c:13]1[cH:14][cH:15][cH:16][cH:17][cH:18]1)[c:29]1[n:30][cH:31][c:32]([N+:35](=[O:36])[O-:37])[cH:33][cH:34]1)(=[O:19])[O:20][CH2:21][c:22]1[cH:23][cH:24][cH:25][cH:26][cH:27]1

Participants

6

Reactant 5

HCID 679Dimethyl SulfoxideHCID 813Potassium CationHCID 783082-Chloro-5-nitropyridineHCID 84754Dibenzyl malonateHCID 45749132-Methylpropan-2-olate

Product 1

HCID 69115439Dibenzyl 5-nitro-2-pyridylmalonate

Sources & evidence

ORD record
ord-f0838eb28d664ecc85c367fc260aa451
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (1/10)

Reaction notes

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