Toluene → 2-(1,3-dioxolan-2-yl)-6,7-dihydro-5H-thieno[3,2-b]pyran

HRID 1550733Notes

Reaction equation

HRID 1550733 reaction equation
[Br:1][c:2]1[c:3]([CH2:12][CH2:13][CH2:14][OH:15])[s:4][c:5]([CH:7]2[O:8][CH2:9][CH2:10][O:11]2)[cH:6]1.[C:16](=[O:17])([O-:18])[O-:19].[CH3:22][c:23]1[cH:24][cH:25][cH:26][cH:27][cH:28]1.[Cs+:20].[Cs+:21]>>[c:2]12[c:3]([s:4][c:5]([CH:7]3[O:8][CH2:9][CH2:10][O:11]3)[cH:6]1)[CH2:12][CH2:13][CH2:14][O:15]2

Participants

5

Reactant 4

HCID 1140TolueneHCID 19660Carbonate IonHCID 104967Cesium cation2×HCID 574869113-[3-Bromo-5-(1,3-dioxolan-2-yl)-2-thienyl]-1-propanol

Product 1

HCID 574869122-(1,3-dioxolan-2-yl)-6,7-dihydro-5H-thieno[3,2-b]pyran

Sources & evidence

ORD record
ord-611c0da7abe8462da5875dfe7d6cd0f7
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (1/10)

Reaction notes

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