Bromide ion → 2-Benzyl-5-methoxy-8-methylene-1,2,3,3a,8,8a-hexahydroindeno[1,2-c]pyrrole

HRID 155183Notes

Reaction equation

HRID 155183 reaction equation
[Br-:29].[CH2:7]([c:8]1[cH:9][cH:10][cH:11][cH:12][cH:13]1)[N:14]1[CH2:15][CH:16]2[CH:17]([c:18]3[cH:19][c:20]([O:26][CH3:27])[cH:21][cH:22][c:23]3[C:24]2=[O:25])[CH2:28]1.[CH3:1][C:2]([CH3:3])([O-:4])[CH3:5].[CH3:30][P+:31]([c:32]1[cH:33][cH:34][cH:35][cH:36][cH:37]1)([c:38]1[cH:39][cH:40][cH:41][cH:42][cH:43]1)[c:44]1[cH:45][cH:46][cH:47][cH:48][cH:49]1.[K+:6]>>[CH2:1]=[C:24]1[CH:16]2[CH2:15][N:14]([CH2:7][c:8]3[cH:9][cH:10][cH:11][cH:12][cH:13]3)[CH2:28][CH:17]2[c:18]2[cH:19][c:20]([O:26][CH3:27])[cH:21][cH:22][c:23]21

Participants

6

Reactant 5

HCID 259Bromide ionHCID 813Potassium CationHCID 74506TriphenylmethylphosphoniumHCID 45749132-Methylpropan-2-olateHCID 672034582-Benzyl-5-methoxy-2,3,3a,8a-tetrahydro-1H-2-aza-cyclopenta[a]inden-8-one

Product 1

HCID 672038462-Benzyl-5-methoxy-8-methylene-1,2,3,3a,8,8a-hexahydroindeno[1,2-c]pyrrole

Sources & evidence

ORD record
ord-62f7a71e08474711bd9c036b5cb5626d
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (9/10)

Reaction notes

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