Acetate → 3-(3-Hydroxy-4-methoxyphenyl)prop-2-enal

HRID 1553750Notes

Reaction equation

HRID 1553750 reaction equation
[C:37]([O:38][C:39](=[O:40])[C:41]([CH3:42])([CH3:43])[CH3:44])(=[O:45])[C:46]([CH3:47])([CH3:48])[CH3:49].[C:52]([O-:53])(=[O:54])[CH3:55].[C:57]([O-:58])(=[O:59])[CH3:60].[H:50][H:51].[OH:23][c:24]1[cH:25][c:26]([CH:27]=[CH:28][C:29](=[O:30])[OH:31])[cH:32][cH:33][c:34]1[O:35][CH3:36].[Pd+2:56].[c:1]1([CH3:2])[cH:3][cH:4][c:5]([P:6]([c:7]2[cH:8][cH:9][c:10]([CH3:11])[cH:12][cH:13]2)[c:14]2[cH:15][cH:16][c:17]([CH3:18])[cH:19][cH:20]2)[cH:21][cH:22]1>>[OH:23][c:24]1[cH:25][c:26]([CH:27]=[CH:28][CH:29]=[O:30])[cH:32][cH:33][c:34]1[O:35][CH3:36]

Participants

7

Reactant 6

HCID 175Acetate2×HCID 13956Phosphine, tris(4-methylphenyl)-HCID 15234Pivalic anhydrideHCID 921263-(3-Hydroxy-4-methoxyphenyl)prop-2-enoic acidHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 178418361HCID 178418361, compound

Product 1

HCID 540251573-(3-Hydroxy-4-methoxyphenyl)prop-2-enal

Sources & evidence

ORD record
ord-d4f958eb695a429d97ddf6b3fd70d3c5
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (1/10)

Reaction notes

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