Potassium Cation → 4-tert-Butyl 4'-methyl 2,6-diethoxybiphenyl-4,4'-dicarboxylate

HRID 1564725Notes

Reaction equation

HRID 1564725 reaction equation
[Br:15][c:16]1[c:17]([O:32][CH2:33][CH3:34])[cH:18][c:19]([C:20](=[O:21])[O:22][C:23]([CH3:24])([CH3:25])[CH3:26])[cH:27][c:28]1[O:29][CH2:30][CH3:31].[CH3:2][O:3][C:4](=[O:5])[c:6]1[cH:7][cH:8][c:9]([B:12]([OH:13])[OH:14])[cH:10][cH:11]1.[CH3:43][O:44][CH2:45][CH2:46][O:47][CH3:48].[K+:40].[K+:41].[K+:42].[OH2:1].[P:35]([O-:36])([O-:37])([O-:38])=[O:39]>>[CH3:2][O:3][C:4](=[O:5])[c:6]1[cH:7][cH:8][c:9](-[c:16]2[c:17]([O:32][CH2:33][CH3:34])[cH:18][c:19]([C:20](=[O:21])[O:22][C:23]([CH3:24])([CH3:25])[CH3:26])[cH:27][c:28]2[O:29][CH2:30][CH3:31])[cH:10][cH:11]1

Participants

7

Reactant 6

HCID 813Potassium Cation3×HCID 962WaterHCID 1061PhosphateHCID 80711,2-DimethoxyethaneHCID 27343694-Methoxycarbonylphenylboronic acidHCID 57930980Tert-butyl 4-bromo-3,5-diethoxybenzoate

Product 1

HCID 670555564-tert-Butyl 4'-methyl 2,6-diethoxybiphenyl-4,4'-dicarboxylate

Sources & evidence

ORD record
ord-e27bb10f4ad1489186946abd335d6760
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (1/10)

Reaction notes

Loading…