Ethanol → 10,13-dimethyl-17-(2-methyl-1,3-dioxolan-2-yl)-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydro-1H-cyclopenta[a]phenanthren-11-ol

HRID 1567053Notes

Reaction equation

HRID 1567053 reaction equation
[BH4-:27].[CH2:1]1[O:2][C:3]([CH3:4])([CH:5]2[CH2:6][CH2:7][CH:8]3[CH:9]4[CH2:10][CH2:11][CH:12]5[CH2:13][CH:14]=[CH:15][CH2:16][C:17]5([CH3:18])[CH:19]4[C:20](=[O:24])[CH2:21][C:22]23[CH3:23])[O:25][CH2:26]1.[CH3:29][CH2:30][OH:31].[Na+:28].[OH2:32]>>[CH2:1]1[O:2][C:3]([CH3:4])([CH:5]2[CH2:6][CH2:7][CH:8]3[CH:9]4[CH2:10][CH2:11][CH:12]5[CH2:13][CH:14]=[CH:15][CH2:16][C:17]5([CH3:18])[CH:19]4[CH:20]([OH:24])[CH2:21][C:22]23[CH3:23])[O:25][CH2:26]1

Participants

6

Reactant 5

HCID 702EthanolHCID 923Sodium ionHCID 962WaterHCID 28123BorohydrideHCID 178421538HCID 178421538, compound

Product 1

HCID 17842153910,13-dimethyl-17-(2-methyl-1,3-dioxolan-2-yl)-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydro-1H-cyclopenta[a]phenanthren-11-ol

Sources & evidence

ORD record
ord-54aaabbf690a41dc88a0311d0e5b57da
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (1/10)

Reaction notes

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