HRID1568299

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID813

Potassium cation

K+

HCID961

Hydroxide

HO-

HCID3283

Diethyl Ether

C4H10O

HCID23938

Palladium

2 次

HCID95417

1,5-Diphenyl-1,4-pentadien-3-one

C17H14O

3 次

结构：CC(C)c1cc(C(C)C)c(-c2ccccc2P(C(C)(C)C)C(C)(C)C)c(C(C)C)c1

HCID11618717

2-Di-tert-butylphosphino-2',4',6'-triisopropylbiphenyl

C29H45P

HCID58111158

未命名化合物

PRODUCTS

生成物

HCID57930116

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-d5e4da07d8934f6587d250ea00faad6a
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (1/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (1/10)

反应 SMILES

[Br:1][c:2]1[cH:3][cH:4][c:5]([C:8]2=[CH:13][CH2:12][N:11]([S:14](=[O:15])(=[O:16])[CH3:17])[CH2:10][CH2:9]2)[cH:6][cH:7]1.[C:20]([P:21]([C:22]([CH3:23])([CH3:24])[CH3:25])[c:26]1[cH:27][cH:28][cH:29][cH:30][c:31]1-[c:32]1[c:33]([CH:34]([CH3:35])[CH3:36])[cH:37][c:38]([CH:39]([CH3:40])[CH3:41])[cH:42][c:43]1[CH:44]([CH3:45])[CH3:46])([CH3:47])([CH3:48])[CH3:49].[CH3:106][CH2:107][O:108][CH2:109][CH3:110].[K+:19].[O:52]=[C:53]([CH:54]=[CH:55][c:56]1[cH:57][cH:58][cH:59][cH:60][cH:61]1)[CH:62]=[CH:63][c:64]1[cH:65][cH:66][cH:67][cH:68][cH:69]1.[O:70]=[C:71]([CH:72]=[CH:73][c:74]1[cH:75][cH:76][cH:77][cH:78][cH:79]1)[CH:80]=[CH:81][c:82]1[cH:83][cH:84][cH:85][cH:86][cH:87]1.[O:88]=[C:89]([CH:90]=[CH:91][c:92]1[cH:93][cH:94][cH:95][cH:96][cH:97]1)[CH:98]=[CH:99][c:100]1[cH:101][cH:102][cH:103][cH:104][cH:105]1.[OH-:18].[Pd:50].[Pd:51]>>[c:2]1([OH:18])[cH:3][cH:4][c:5]([C:8]2=[CH:13][CH2:12][N:11]([S:14](=[O:15])(=[O:16])[CH3:17])[CH2:10][CH2:9]2)[cH:6][cH:7]1