HRID1569906

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID795

Imidazole

C3H4N2

HCID28928

Chloro(1,1-dimethylethyl)dimethylsilane

C6H15ClSi

结构：CC(=O)OI1(OC(C)=O)(OC(C)=O)OC(=O)c2ccccc21

HCID159087

Triacetoxyperiodinane

C13H13IO8

HCID18769086

未命名化合物

PRODUCTS

生成物

结构：CNC(=O)c1c(O[Si](C)(C)C(C)(C)C)ccc2cc(Br)ccc12

HCID18769155

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-fc88c266a6344a62b212092f54a732f8
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (1/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (1/10)

反应 SMILES

[Br:1][c:2]1[cH:3][c:4]2[cH:5][cH:6][c:7]([OH:16])[c:8]([C:12](=[O:13])[NH:14][CH3:15])[c:9]2[cH:10][cH:11]1.[C:17]([CH3:18])([CH3:19])([CH3:20])[Si:21]([CH3:22])([CH3:23])[Cl:24].[CH3:30][C:31]([O:32][I:33]1([O:43][C:44]([CH3:45])=[O:46])([O:47][C:48]([CH3:49])=[O:50])[c:34]2[c:35]([cH:36][cH:37][cH:38][cH:39]2)[C:40](=[O:41])[O:42]1)=[O:51].[nH:25]1[cH:26][cH:27][n:28][cH:29]1>>[Br:1][c:2]1[cH:3][c:4]2[cH:5][cH:6][c:7]([O:16][Si:21]([C:17]([CH3:18])([CH3:19])[CH3:20])([CH3:22])[CH3:23])[c:8]([C:12](=[O:13])[NH:14][CH3:15])[c:9]2[cH:10][cH:11]1