Acetate → 2-Methyl-7-(2-furanyl)-1-indanone

HRID 157107Notes

Reaction equation

HRID 157107 reaction equation
[Br:1][c:2]1[cH:3][cH:4][cH:5][c:6]2[c:10]1[C:9](=[O:11])[CH:8]([CH3:12])[CH2:7]2.[C:73]([O-:74])(=[O:75])[CH3:76].[C:78]([O-:79])(=[O:80])[CH3:81].[CH2:67]([CH2:68][O:69][CH3:70])[O:71][CH3:72].[Na+:21].[Na+:22].[O-:23][C:24](=[O:25])[O-:26].[OH2:82].[Pd+2:77].[c:27]1([CH3:28])[cH:29][cH:30][cH:31][cH:32][c:33]1-[c:34]1[cH:35][cH:36][cH:37][cH:38][c:39]1[P:40]([c:41]1[cH:42][cH:43][cH:44][cH:45][c:46]1-[c:47]1[cH:48][cH:49][cH:50][cH:51][c:52]1[CH3:53])[c:54]1[cH:55][cH:56][cH:57][cH:58][c:59]1-[c:60]1[cH:61][cH:62][cH:63][cH:64][c:65]1[CH3:66].[o:13]1[c:14]([B:18]([OH:19])[OH:20])[cH:15][cH:16][cH:17]1>>[c:2]1(-[c:14]2[o:13][cH:17][cH:16][cH:15]2)[cH:3][cH:4][cH:5][c:6]2[c:10]1[C:9](=[O:11])[CH:8]([CH3:12])[CH2:7]2

Participants

10

Reactant 9

HCID 175Acetate2×HCID 923Sodium ion2×HCID 962WaterHCID 80711,2-DimethoxyethaneHCID 19660Carbonate IonHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 2734357Furan-2-boronic acidHCID 158697837-Bromo-2-methyl-2,3-dihydro-1H-inden-1-oneHCID 22172997Tris(o-tolylphenyl)phosphine

Product 1

HCID 221733462-Methyl-7-(2-furanyl)-1-indanone

Sources & evidence

ORD record
ord-1feabcfe557d43719eac6608c4bfa8b3
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (9/10)

Reaction notes

Loading…