N,N-Dimethylaniline → Benzenamine, N,N-dimethyl-, sulfate (1:1)
Reaction equation
S(=O)(O)O.[CH3:5][N:6]([CH3:13])[C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1.S(=O)=O.[S:17](=[O:21])(=[O:20])([OH:19])[OH:18]>>[S:17]([OH:21])([OH:20])(=[O:19])=[O:18].[CH3:5][N:6]([CH3:13])[C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1Participants
Procedure
The uprising effluent gas leaves the sulfurous acid scrubbing section 9 still containing a small amount of residual gaseous dimethylaniline as well as a small amount of sulfur dioxide gas, and enters and passes upwardly within sulfuric acid scrubbing section 10, wherein the gas is bubbled through a descending current of dilute sulfuric acid aqueous solution typically of 10% sulfuric acid concentration which is introduced into the upper portion of sulfuric acid scrubber 10 above the uppermost tray therein through conduit 23. All or substantially all of the residual gaseous dimethylaniline is removed from the sulfur dioxide-impoverished gas in scrubbing section 10 by reaction with the sulfuric acid to form dimethylaniline sulfate. The tail gas exits from sulfuric acid scrubber 10 via line 18 and typically contains less than 0.10% by volume sulfur dioxide. Dilute liquid aqueous sulfuric acid solution containing the thus-formed dimethylaniline sulfate is removed from the lowermost tray in scrubbing section 10 and passed through line 64 to recycle tank 65.
Workup
- customis bubbled through a descending current of dilute sulfuric acid aqueous solution
- concentrationtypically of 10% sulfuric acid concentration which
- additionis introduced into the upper portion of sulfuric acid scrubber 10 above the uppermost tray
- customAll or substantially all of the residual gaseous dimethylaniline is removed from the sulfur dioxide-impoverished gas in scrubbing section 10 by reaction with the sulfuric acid
Sources & evidence
- ORD record
- ord-da81258dd94a49908055beb0cb014482
- Source dataset
- uspto-grants-1976_09
- Patent number
- US03980760
Reaction notes
Loading…