Vanadium trichloride oxide → HCID 178478237, compound

HRID 1576574Notes

Reaction equation

HRID 1576574 reaction equation
[O:1]=[V:2].[ClH:3].[ClH:4].[ClH:5].[Cl:6][C:7]1[CH:12]=[CH:11][C:10]([Si:13]([C:22]2[CH:27]=[CH:26][C:25]([Cl:28])=[CH:24][CH:23]=2)([C:15]2[CH:20]=[CH:19][C:18]([Cl:21])=[CH:17][CH:16]=2)[OH:14])=[CH:9][CH:8]=1>>[O-2:14].[Cl:21][C:18]1[CH:19]=[CH:20][C:15]([Si:13]([C:22]2[CH:27]=[CH:26][C:25]([Cl:28])=[CH:24][CH:23]=2)([C:10]2[CH:11]=[CH:12][C:7]([Cl:6])=[CH:8][CH:9]=2)[O:14][V+2:2]([O:14][Si:13]([C:22]2[CH:27]=[CH:26][C:25]([Cl:28])=[CH:24][CH:23]=2)([C:10]2[CH:11]=[CH:12][C:7]([Cl:6])=[CH:8][CH:9]=2)[C:15]2[CH:20]=[CH:19][C:18]([Cl:21])=[CH:17][CH:16]=2)[O:1][Si:13]([C:15]2[CH:16]=[CH:17][C:18]([Cl:5])=[CH:19][CH:20]=2)([C:22]2[CH:27]=[CH:26][C:25]([Cl:4])=[CH:24][CH:23]=2)[C:10]2[CH:9]=[CH:8][C:7]([Cl:3])=[CH:12][CH:11]=2)=[CH:16][CH:17]=1

Participants

3

Reactant 2

HCID 24410Vanadium trichloride oxideHCID 21324931Tris(4-chlorophenyl)silanol

Product 1

HCID 178478237HCID 178478237, compound

Procedure

vanadium oxytrichloride is reacted with tri-(p-chlorophenyl)-silanol [m.p. 127°-128°C] to produce tris-[tri-(p-chlorophenyl)-siloxy]vanadium oxide [m.p. 181°C.]; vanadium oxytrichloride is reacted with tri-(p-bromophenyl)-silanol [m.p. 120°-121°C.] to produce the tris-[tri-(p-bromophenyl)-silox]-vanadium oxide [m.p. 175°C.]; and vanadium oxytrichloride is reacted with tri-4-biphenylyl-silanol [m.p. 199°-200°C.] to produce tris-[tri-(4-biphenylyl)-siloxy]-vanadium oxide.

Sources & evidence

ORD record
ord-28eb73bac8a341fb929f1abcb8bb1ee0
Source dataset
uspto-grants-1976_09
Patent number
US03981896

Reaction notes

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