HRID1576575

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID24410

未命名化合物

结构：O[Si](c1ccc(-c2ccccc2)cc1)(c1ccc(-c2ccccc2)cc1)c1ccc(-c2ccccc2)cc1

HCID3521950

未命名化合物

PRODUCTS

生成物

结构：[O-2].c1ccc(-c2ccc([Si](O[V+2](O[Si](c3ccc(-c4ccccc4)cc3)(c3ccc(-c4ccccc4)cc3)c3ccc(-c4ccccc4)cc3)O[Si](c3ccc(-c4ccccc4)cc3)(c3ccc(-c4ccccc4)cc3)c3ccc(-c4ccccc4)cc3)(c3ccc(-c4ccccc4)cc3)c3ccc(-c4ccccc4)cc3)cc2)cc1

HCID178514808

未命名化合物

PROCEDURE

实验过程

vanadium oxytrichloride is reacted with tri-(p-chlorophenyl)-silanol [m.p. 127°-128°C] to produce tris-[tri-(p-chlorophenyl)-siloxy]vanadium oxide [m.p. 181°C.]; vanadium oxytrichloride is reacted with tri-(p-bromophenyl)-silanol [m.p. 120°-121°C.] to produce the tris-[tri-(p-bromophenyl)-silox]-vanadium oxide [m.p. 175°C.]; and vanadium oxytrichloride is reacted with tri-4-biphenylyl-silanol [m.p. 199°-200°C.] to produce tris-[tri-(4-biphenylyl)-siloxy]-vanadium oxide.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-6acb962f25644d279d700badb246aec7
来源数据集: uspto-grants-1976_09
DOI: 10.6084/m9.figshare.5104873.v1
专利: US03981896
来源说明: uspto-grants-1976_09

反应 SMILES

[O:1]=[V:2].Cl.Cl.Cl.[C:6]1([C:38]2[CH:43]=[CH:42][CH:41]=[CH:40][CH:39]=2)[CH:11]=[CH:10][C:9]([Si:12]([C:26]2[CH:31]=[CH:30][C:29]([C:32]3[CH:37]=[CH:36][CH:35]=[CH:34][CH:33]=3)=[CH:28][CH:27]=2)([C:14]2[CH:19]=[CH:18][C:17]([C:20]3[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=3)=[CH:16][CH:15]=2)[OH:13])=[CH:8][CH:7]=1>>[O-2:13].[C:17]1([C:20]2[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=2)[CH:16]=[CH:15][C:14]([Si:12]([C:26]2[CH:31]=[CH:30][C:29]([C:32]3[CH:37]=[CH:36][CH:35]=[CH:34][CH:33]=3)=[CH:28][CH:27]=2)([C:9]2[CH:10]=[CH:11][C:6]([C:38]3[CH:39]=[CH:40][CH:41]=[CH:42][CH:43]=3)=[CH:7][CH:8]=2)[O:13][V+2:2]([O:13][Si:12]([C:26]2[CH:31]=[CH:30][C:29]([C:32]3[CH:37]=[CH:36][CH:35]=[CH:34][CH:33]=3)=[CH:28][CH:27]=2)([C:9]2[CH:10]=[CH:11][C:6]([C:38]3[CH:39]=[CH:40][CH:41]=[CH:42][CH:43]=3)=[CH:7][CH:8]=2)[C:14]2[CH:15]=[CH:16][C:17]([C:20]3[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=3)=[CH:18][CH:19]=2)[O:1][Si:12]([C:26]2[CH:27]=[CH:28][C:29]([C:32]3[CH:33]=[CH:34][CH:35]=[CH:36][CH:37]=3)=[CH:30][CH:31]=2)([C:14]2[CH:19]=[CH:18][C:17]([C:20]3[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=3)=[CH:16][CH:15]=2)[C:9]2[CH:10]=[CH:11][C:6]([C:38]3[CH:39]=[CH:40][CH:41]=[CH:42][CH:43]=3)=[CH:7][CH:8]=2)=[CH:19][CH:18]=1