HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-Methylpyridine → 1,1,1,3,3,3-Hexafluoro-2-(trifluoromethyl)propan-2-yl 2-methylprop-2-enoate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-Methylpyridine | HCID 7975 | — |
| Reactant | Methacryloyl chloride | HCID 13528 | — |
| Reactant | Perfluoro-tert-butyl alcohol | HCID 16924 | — |
| Product | 1,1,1,3,3,3-Hexafluoro-2-(trifluoromethyl)propan-2-yl 2-methylprop-2-enoate | HCID 21701052 | 78% |
Reaction Steps
Perfluoro-tertiary-butyl methacrylate was prepared from perfluoro-tertiary-butyl alcohol and methacrylyl chloride with 2-methyl pyridine as the acid acceptor without added solvent. The yield was 78%. The boiling point was 30°C./0.5 mm. This material is useful as a monomer for making plastics and resins.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03981928 |
| Source dataset | uspto-grants-1976_09 |
| ORD ID | ord-c61cc3ac5a9f4460bae971bf269082dc |
| Source note | uspto-grants-1976_09 |