HuagongsheHuagongshe Chemistry Print Report · For research reference only
Diethyl Ether → 1a,2,7,7a-Tetrahydronaphtho[2,3-b]oxiren-3-ol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Diethyl Ether | HCID 3283 | — |
| Reactant | m-Chloroperbenzoic acid | HCID 70297 | — |
| Reactant | 5,8-Dihydro-1-naphthol | HCID 97466 | — |
| Reactant | Sodium Bicarbonate | HCID 516892 | — |
| Solvent | Ethyl Acetate | HCID 8857 | — |
| Product | 1a,2,7,7a-Tetrahydronaphtho[2,3-b]oxiren-3-ol | HCID 12445737 | — |
Reaction Steps
prepared as described hereinbefore, by mixing a cooled solution (temperature less than about 30°C.) of 5,8-dihydro-1-naphthol in ethyl acetate with m-chloroperbenzoic acid and mixing the resulting slurry with a mixture of ethyl ether and aqueous sodium bicarbonate, to form 5,6,7,8-tetrahydro-6,7-epoxy-1-naphthol ##SPC27##
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03982021 |
| Source dataset | uspto-grants-1976_09 |
| ORD ID | ord-64b225046a1a4f7cbffe16dbf385281c |
| Source note | uspto-grants-1976_09 |