HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dimethylamine → Hexazinone
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dimethylamine | HCID 674 | — |
| Reactant | 3-Cyclohexyl-1-methyl-6-(methylsulfanyl)-1,3,5-triazine-2,4(1H,3H)-dione | HCID 13296080 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | Hexazinone | HCID 39965 | — |
Reaction Steps
A suspension of 300 parts of 1-methyl-3-cyclohexyl-6-methylthio-s-triazine-2,4(1H,3H)-dione in 887 parts of toluene is stirred at 25°-30° for three hours with 150 parts of dimethylamine. Toluene is distilled from the reaction until a pot temperature of 125° is attained. The reaction mass is cooled to 50° at which time 480 parts of hexane is added over 0.66 hours. The slurry at 25° is filtered to give 282 parts of crystalline 1-methyl-3-cyclohexyl-6-dimethylamino-s-triazine-2,4(1H,3H)-dione, m.p. 110°-115°.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03983116 |
| Source dataset | uspto-grants-1976_09 |
| ORD ID | ord-bf3c393e45574de496b123cc50993fb7 |
| Source note | uspto-grants-1976_09 |