HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Acetylcyclohexene → 2,3,4,4a,6,7,11b,12,13,13a-decahydro-9-methyl-1H-dibenzo[a,f]quinolizin-13-one
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Acetylcyclohexene | HCID 13612 | — |
| Reactant | 1-Propanone, 1-(1-cyclohexen-1-yl)- | HCID 573011 | — |
| Reactant | 3,4-Dihydroisoquinoline--hydrogen chloride (1/1) | HCID 20463855 | — |
| Reactant | 3,4-Dihydro-6-methylisoquinoline hydrochloride | HCID 21509910 | — |
| Product | 2,3,4,4a,6,7,11b,12,13,13a-decahydro-9-methyl-1H-dibenzo[a,f]quinolizin-13-one | HCID 21509912 | — |
Reaction Steps
when in Example 1 an appropriate amount of 3,4-dihydro-6-methylisoquinoline hydrochloride and 1-cyclohexen-1-yl methyl ketone are substituted for 3,4-dihydroisoquinoline hydrochloride and 1-cyclohexen-1-yl ethyl ketone respectively, 2,3,4,4a,6,7,11b,12,13,13a-decahydro-9-methyl-1H-dibenzo[a,f]quinolizin-13-one is obtained, M.P. 101°-121°C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03983122 |
| Source dataset | uspto-grants-1976_09 |
| ORD ID | ord-597f46fd62da4a909b34a21d56b2f554 |
| Source note | uspto-grants-1976_09 |