HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Acetylcyclohexene → 2,3,4,4a,6,7,11b,12,13,13a-decahydro-9,10-dimethoxy-1H-dibenzo[a,f]quinolizin-13-one
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Acetylcyclohexene | HCID 13612 | — |
| Reactant | 3,4-Dihydroisoquinoline | HCID 76705 | — |
| Reactant | 1-Acetylcyclopentene | HCID 192925 | — |
| Reactant | 3,4-Dihydro-6,7-dimethoxyisoquinoline hydrochloride | HCID 2724664 | — |
| Product | 2,3,4,4a,6,7,11b,12,13,13a-decahydro-9,10-dimethoxy-1H-dibenzo[a,f]quinolizin-13-one | HCID 12774492 | — |
Reaction Steps
When in Example 6 appropriate amounts of 3,4-dihydro-6,7 -dimethoxyisoquinoline hydrochloride and 1-cyclohexen-1-yl methyl ketone respectively are substituted for 3,4-dihydroisoquinoline and 1-cyclopenten-1-yl methyl ketone, 2,3,4,4a,6,7,11b,12,13,13a-decahydro-9,10-dimethoxy-1H-dibenzo[a,f]quinolizin-13-one is obtained, M.P. 129°-141°C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03983122 |
| Source dataset | uspto-grants-1976_09 |
| ORD ID | ord-b50c4a3134534b4eb5d8e13656d6a958 |
| Source note | uspto-grants-1976_09 |