(4-(Benzyloxy)phenyl)methanol → Benzaldehyde, 4-(phenylmethoxy)-

HRID 1576927Notes

Reaction equation

HRID 1576927 reaction equation
[OH:1][CH2:2][C:3]1[CH:16]=[CH:15][C:6]([O:7][CH2:8][C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)=[CH:5][CH:4]=1>CC(C)=O.[O-2].[O-2].[Mn+4]>[CH:2]([C:3]1[CH:16]=[CH:15][C:6]([O:7][CH2:8][C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)=[CH:5][CH:4]=1)=[O:1]

Participants

4

Reactant 1

HCID 70043(4-(Benzyloxy)phenyl)methanol

Product 1

HCID 78109Benzaldehyde, 4-(phenylmethoxy)-

Reagents, catalysts & solvents 2

HCID 178418406HCID 178418406, compoundCatalystHCID 180AcetoneSolvent

Procedure

A mixture of 4-hydroxymethylphenoxy phenyl methane (1.07g.; 0.005 mole) and active manganese dioxide (0.44g.; 0.005 mole) in dry acetone (20ml) was stirred under dry nitrogen for 18 hrs. at room temperature. The inorganic salts were then filtered off to yield 4-formylphenoxy phenyl methane identified by TLC.

Workup

  1. customat room temperature
  2. filtrationThe inorganic salts were then filtered off

Sources & evidence

ORD record
ord-a96825d6992542a194001df2cb01b3f4
Source dataset
uspto-grants-1976_09
Patent number
US03983164

Reaction notes

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