Chlorosulfonic acid → HCID 53734201, compound

HRID 1577063Notes

Reaction equation

HRID 1577063 reaction equation
[Cl:1]C1C(=O)NC(=O)C1(S(O)(=O)=O)C1C=CC=CC=1.Cl[S:20]([OH:23])(=[O:22])=[O:21].[CH2:24]([C:31]1[C:32]([NH:34][C:35](=[O:37])[CH:36]=1)=[O:33])[C:25]1[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=1>>[Cl:1][N:34]1[C:35](=[O:37])[C:36]([S:20]([OH:23])(=[O:22])=[O:21])=[C:31]([CH2:24][C:25]2[CH:26]=[CH:27][CH:28]=[CH:29][CH:30]=2)[C:32]1=[O:33]

Participants

4

Reactant 3

HCID 24638Chlorosulfonic acidHCID 19810774HCID 19810774, compoundHCID 54567916HCID 54567916, compound

Product 1

HCID 53734201HCID 53734201, compound

Procedure

In the apparatus mentioned under (b), 87.4 g (0.75 mol) of chlorosulfonic acid and 18.7 g (0.1 mol) of benzylmaleimide are mixed together for 5 hours at 60° C. The solution is afterwards added dropwise to ice water, and the mixture is stirred for 30 minutes. The mixture is then extracted with methylene chloride as described under (b). The initially liquid product slowly crystallises on standing.

Workup

  1. additionare mixed together for 5 hours at 60° C
  2. extractionThe mixture is then extracted with methylene chloride
  3. customThe initially liquid product slowly crystallises

Sources & evidence

ORD record
ord-088cdfa59f13452c89566d410a7ce06d
Source dataset
uspto-grants-1981_09
Patent number
US04287106

Reaction notes

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