HuagongsheHuagongshe Chemistry Print Report · For research reference only
Myrcene → (Z)-2,6-dimethyloct-2-ene-1,8-diol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Myrcene | HCID 31253 | — |
| Reactant | Sodium Acetate | HCID 517045 | — |
| Reactant | Calcium Hydroxide | HCID 6093208 | — |
| Reactant | Dichloro di-methyloctene | HCID 20571628 | — |
| Solvent | Benzene | HCID 241 | — |
| Solvent | Triethylamine | HCID 8471 | — |
| Product | (Z)-2,6-dimethyloct-2-ene-1,8-diol | HCID 77134639 | — |
Reaction Steps
Prod.: (many methods) e.g. from Myrcene, via Myrcene dihydrochloride to Dichloro di-methyloctene. This is converted to Chloro di-hydrogeranyl acetate (andneryl acetate) with Sodium Acetate in Benzene in presence of Triethylamine. The acetates are saponified with Calcium hydroxide to yield Hydroxycitronellol, from which the aldehyde is prepared by oxidation.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04287133 |
| Source dataset | uspto-grants-1981_09 |
| ORD ID | ord-7b27676bc8cf4c59a57c0fbff246c8fa |
| Source note | uspto-grants-1981_09 |