Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | 1-Chloro-2-nitrobenzene | HCID 6945 | — |
| Reactant | Potassium Fluoride | HCID 522689 | — |
| Reactant | HCID 20572340 | HCID 20572340 | — |
| Product | Nitrobenzene | HCID 7416 | 0.4% |
| Product | 1-Fluoro-2-nitrobenzene | HCID 73895 | — |
Reaction Steps
Potassium fluoride (69.6 g; 1.2 mole) and undecyltributylammonium bromide (25.2 g; 0.06 mole) were added to molten 2-chloronitrobenzene (157.5 g; 1.0 mole). After stirring at 145° C. for 24 hours and a similar work-up to Example 1, 2-fluoronitrobenzene was obtained in 84.6% yield, together with 0.4% nitrobenzene.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US04287374 |
|---|
| Source dataset | uspto-grants-1981_09 |
|---|
| ORD ID | ord-1a0ad1111ab4410b83f7684a64bd4262 |
|---|
| Source note | uspto-grants-1981_09 |
|---|
