HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Bicyclo(2.2.1)heptane-2-carboxylic acid, 3,3-dimethyl- → Camphene
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Bicyclo(2.2.1)heptane-2-carboxylic acid, 3,3-dimethyl- | HCID 99843 | — |
| Edukt | 2,2-Dimethyl-3-methylenebicyclo(2.2.1)heptane-1-carboxylic acid | HCID 3637451 | — |
| Produkt | Camphene | HCID 6616 | — |
Reaktionsschritte
3.3-Dimethylbicyclo-[2.2.1]-heptane-2-carboxylic acid, further to be called camphenic acid, has been described in Bull. Soc. Chim. France 1972 (no. 12) pages 4770-4777, as an intermediate in the synthesis of the corresponding alcohol. Further the synthesis of this compound has been described in Monatshefte fur Chemie 107, page 945 (1976), wherein is stated that it is an important starting material for the preparation of e.g. bicyclic fragrances. In Nippon Kagaku Zasshi 85, pages 593-597 (1964) it is stated that e.g. camphenic acid can be obtained by oxidation of camphene by peracids; see Chem. Abstr. 62, 11858c (1965).
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US04288349 |
| Quelldatensatz | uspto-grants-1981_09 |
| ORD ID | ord-60dc819f6582484897187332c6ebba06 |
| Quellennotiz | uspto-grants-1981_09 |