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HRID 1577473Erstellt: 25. Oktober 2026

Bicyclo(2.2.1)heptane-2-carboxylic acid, 3,3-dimethyl- → Camphene

https://huagongshe.com/reaction/1577473

Reaktionsgleichung

Beteiligte Stoffe

RolleNameHCIDEinwaage
EduktBicyclo(2.2.1)heptane-2-carboxylic acid, 3,3-dimethyl-HCID 99843—
Edukt2,2-Dimethyl-3-methylenebicyclo(2.2.1)heptane-1-carboxylic acidHCID 3637451—
ProduktCampheneHCID 6616—

Reaktionsschritte

3.3-Dimethylbicyclo-[2.2.1]-heptane-2-carboxylic acid, further to be called camphenic acid, has been described in Bull. Soc. Chim. France 1972 (no. 12) pages 4770-4777, as an intermediate in the synthesis of the corresponding alcohol. Further the synthesis of this compound has been described in Monatshefte fur Chemie 107, page 945 (1976), wherein is stated that it is an important starting material for the preparation of e.g. bicyclic fragrances. In Nippon Kagaku Zasshi 85, pages 593-597 (1964) it is stated that e.g. camphenic acid can be obtained by oxidation of camphene by peracids; see Chem. Abstr. 62, 11858c (1965).

Herkunft & Nachweise

DOI10.6084/m9.figshare.5104873.v1
PatentnummerUS04288349
Quelldatensatzuspto-grants-1981_09
ORD IDord-60dc819f6582484897187332c6ebba06
Quellennotizuspto-grants-1981_09