Methanone, (3-hydroxybenzo[b]thien-2-yl)phenyl- → HCID 178449010, compound

HRID 1577553Notes

Reaction equation

HRID 1577553 reaction equation
[C:1]([C:9]1[S:13][C:12]2[CH:14]=[CH:15][CH:16]=[CH:17][C:11]=2[C:10]=1[OH:18])(=O)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.C([O-])(=O)C.[CH3:23][CH:24]([CH3:27])[CH2:25][NH3+:26]>>[CH3:23][CH:24]([CH3:27])[CH2:25][NH:26]/[C:1](/[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1)=[C:9]1\[C:10](=[O:18])[C:11]2[CH:17]=[CH:16][CH:15]=[CH:14][C:12]=2[S:13]\1

Participants

3

Reactant 2

HCID 4712192Methanone, (3-hydroxybenzo[b]thien-2-yl)phenyl-HCID 11434973HCID 11434973, compound

Product 1

HCID 178449010HCID 178449010, compoundYield 69%

Procedure

Prepared as in Example 35 from 2-benzoyl-benzo[b]thiophen-3-ol and (2-methylpropyl)ammonium acetate with a yield of 69% of theory; m.p. 125°-126° C. (ethyl acetate/petroleum ether 1:2).

Sources & evidence

ORD record
ord-3d03b11b6cb044b192fc95a921f16dd7
Source dataset
uspto-grants-1981_09
Patent number
US04288437

Reaction notes

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