2-Chloropropane → 1-(1-Methylethyl)naphthalene

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Reaktionsgleichung

Cl[CH:2]([CH3:4])[CH3:3].[CH:5]1[C:14]2[C:9](=[CH:10][CH:11]=[CH:12][CH:13]=2)[CH:8]=[CH:7][CH:6]=1.ClC(C)C>>[CH:2]([C:13]1[C:14]2[C:9](=[CH:8][CH:7]=[CH:6][CH:5]=2)[CH:10]=[CH:11][CH:12]=1)([CH3:4])[CH3:3]

Komponenten

Edukt 2

HCID 63612-Chloropropane

HCID 86738005Naphthalene 2-chloropropane

Produkt 1

HCID 225351-(1-Methylethyl)naphthalene

Versuchsvorschrift

Reaction was carried out as in Example 4, but using 2-chloropropane as the alkylating agent with a molar ratio of naphthalene/2-chloropropane of 1:0.8. Yield of isopropylnaphthalene obtained was 54%, with an isomer distribution of 98% β- and 2% α-isopropylnaphthalene.

Aufarbeitung

customReaction

Quellen und Nachweise

ORD-Eintrag: ord-78ce770f371a474e94d951a573a7e12f
Quelldatensatz: uspto-grants-1981_09
DOI: 10.6084/m9.figshare.5104873.v1
Patentnummer: US04288646

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