Ammonia → HCID 57093790, compound

HRID 1578138Notes

Reaction equation

HRID 1578138 reaction equation
C([S:4][CH2:5][C:6]([N:8]1[CH2:12][C:11]([CH2:13][C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)=[CH:10][C@H:9]1[C:20]([OH:22])=[O:21])=[O:7])(=O)C.N>>[SH:4][CH2:5][C:6]([N:8]1[CH2:12][C:11]([CH2:13][C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)=[CH:10][C@H:9]1[C:20]([OH:22])=[O:21])=[O:7]

Participants

3

Reactant 2

HCID 222AmmoniaHCID 57257613HCID 57257613, compound

Product 1

HCID 57093790HCID 57093790, compound

Procedure

The product from part (b) is treated with concentrated ammonia according to the procedure of Example 4 to yield (2S)-2,5-dihydro-1-(2-mercapto-1-oxoethyl)-4-(phenylmethyl)-1H-pyrrole-2-carboxylic acid.

Sources & evidence

ORD record
ord-352a7765a379418f9613ae17b0e5c64a
Source dataset
uspto-grants-1981_09
Patent number
US04291040

Reaction notes

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