Ammonia → HCID 57036626, compound

HRID 1578151Notes

Reaction equation

HRID 1578151 reaction equation
C([S:4][CH2:5][CH2:6][C:7]([N:9]1[CH2:13][C:12]([CH2:14][CH2:15][CH2:16][C:17]2[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=2)=[CH:11][C@H:10]1[C:23]([OH:25])=[O:24])=[O:8])(=O)C.N>>[SH:4][CH2:5][CH2:6][C:7]([N:9]1[CH2:13][C:12]([CH2:14][CH2:15][CH2:16][C:17]2[CH:18]=[CH:19][CH:20]=[CH:21][CH:22]=2)=[CH:11][C@H:10]1[C:23]([OH:25])=[O:24])=[O:8]

Participants

3

Reactant 2

HCID 222AmmoniaHCID 57018093HCID 57018093, compound

Product 1

HCID 57036626HCID 57036626, compound

Procedure

The product from part (b) is treated with concentrated ammonia according to the procedure of Example 4 to yield [2S]-2,5-dihydro-1-(3-mercapto-1-oxopropyl)-4-(phenylpropyl)-1H-pyrrole-2-carboxylic acid.

Sources & evidence

ORD record
ord-91c3d36105a444048dc0cdb6ac325bf5
Source dataset
uspto-grants-1981_09
Patent number
US04291040

Reaction notes

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