Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Ethylene | HCID 6325 | — |
| Reactant | 4-Aminoindan | HCID 122569 | — |
| Reactant | Aluminum | HCID 5359268 | — |
| Reactant | Aluminum(III) Chloride | HCID 6451240 | — |
| Product | 5-Ethyl-4-amino-indane | HCID 21559761 | — |
Reaction Steps
A mixture of 106 g (0.8 mole) of 4-amino-indane, 4 g of aluminium chloride and 1.6 g of aluminium shot is heated in an autoclave to 300°C. After injection of ethylene at 200 bar, the reaction mixture is maintained for one hour at 300°C. By distillation of the green-black crude product in high vacuum there is obtained 106.9 g of 5-ethyl-4-amino-indane, B.P. 72 to 74°C/0.001 Torr.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US03936293 |
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| Source dataset | uspto-grants-1976_02 |
|---|
| ORD ID | ord-2e8f77f3abe643c98ca27d10bf38c894 |
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| Source note | uspto-grants-1976_02 |
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