HuagongsheHuagongshe Chemistry Print Report · For research reference only
Oxalic Acid → 1-[2-(2,4-Dichlorophenyl)ethyl]ethanediol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Oxalic Acid | HCID 971 | — |
| Reactant | 1,4-Dioxane | HCID 31275 | — |
| Reactant | 2-[2-(2,4-Dichlorophenyl)ethyl]oxirane | HCID 19813165 | — |
| Solvent | Water | HCID 962 | — |
| Product | 1-[2-(2,4-Dichlorophenyl)ethyl]ethanediol | HCID 20332686 | — |
Reaction Steps
A mixture of 50 parts of [2-(2,4-dichlorophenyl)ethyl]-oxirane, 7 parts of ethanedioic acid, 300 parts of 1,4-dioxane and 150 parts of water is stirred and refluxed for 36 hours. The reaction mixture is evaporated. The residue is crystallized from 2,2'-oxybispropane. The product is filtered off and dried at the air, yielding 1-[2-(2,4-dichlorophenyl)ethyl]ethanediol; mp. 83.2°C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03936470 |
| Source dataset | uspto-grants-1976_02 |
| ORD ID | ord-00928af4c5b546908e29d5a907b5a720 |
| Source note | uspto-grants-1976_02 |