HuagongsheHuagongshe Chemistry Print Report · For research reference only
Water → HCID 515701, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Water | HCID 962 | — |
| Reactant | Sodium Hydroxide | HCID 14798 | — |
| Reactant | N-(3-chloropropyl)piperidine hydrochloride | HCID 79624 | — |
| Reactant | Fluoranthene-3,9-diol | HCID 12546984 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | HCID 515701 | HCID 515701 | — |
Reaction Steps
To 200 ml of water containing 16.0 g (0.4 mole) of sodium hydroxide and 15.7 g (0.067 mole) of 3,9-dihydroxyfluoranthene are added 200 ml of toluene and 29.8 (0.15 mole) of 3-piperidinopropyl chloride hydrochloride and the heterogeneous reaction mixture is stirred at reflux for 24 hours. After cooling, the organic layer is washed with water, dried over magnesium sulfate, and concentrated in vacuo. The residue is crystallized from ether to give 3,9-bis(3-piperidinopropoxy)fluoranthene, M.P. 92°-93°C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03937833 |
| Source dataset | uspto-grants-1976_02 |
| ORD ID | ord-efa69e2f1945429eb43ddefc5b3d666b |
| Source note | uspto-grants-1976_02 |