Tert-Butylbenzene → 1-(4-tert-Butylphenyl)-2-chloropropan-1-one

HRID 1578808Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1578808
[Cl:1][CH:2]([CH3:6])[C:3](Cl)=[O:4].[C:7]([C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1)([CH3:10])([CH3:9])[CH3:8]>>[C:7]([C:11]1[CH:16]=[CH:15][C:14]([C:3](=[O:4])[CH:2]([Cl:1])[CH3:6])=[CH:13][CH:12]=1)([CH3:10])([CH3:9])[CH3:8]

Komponenten

3

Edukt 2

HCID 7366Tert-ButylbenzeneHCID 1110192-Chloropropionyl chloride

Produkt 1

HCID 38186171-(4-tert-Butylphenyl)-2-chloropropan-1-one

Versuchsvorschrift

The procedure of Example 1 was followed for the reaction of 63.5g (0.5 mole) of 2-chloropropionyl chloride with 67g (0.5 mole) of tert-butylbenzene. Obtained after high vacuum concentration was 100g of a clear, yellow liquid product: ir (film) 3.4 (s), 5.9 (s), 6.3 (s), 8.0 (s), 10.5 (s), 11.8 (s) microns: nmr (CDCl3) 7.67 (4H, d of d), 5.21 (1H, q), 1.67 (3H, d), 1.28 (9H, s) ppm. A VPC analysis indicated one pure product.

Aufarbeitung

  1. customObtained
  2. concentrationafter high vacuum concentration

Quellen und Nachweise

ORD-Eintrag
ord-599e6fd7247a49e0b518748dcfbaaf85
Quelldatensatz
uspto-grants-1976_02
Patentnummer
US03939218

Notizen zur Reaktion

Wird geladen…