HRID1579028

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID21432264

未命名化合物

HCID21432269

Ethyl 1-methyl-5-nitro-1H-imidazole-2-carboximidate

C7H10N4O3

HCID178418668

未命名化合物

结构：Cl.N=C(N)NNC(=N)c1ncc([N+](=O)[O-])n1CCO

HCID178479530

未命名化合物

HCID178485182

未命名化合物

PRODUCTS

生成物

结构：CNC(=N)NNC(=N)c1ncc([N+](=O)[O-])n1C.Cl

HCID178485183

未命名化合物

结构：CN(NC(=N)c1ncc([N+](=O)[O-])n1C)C(=N)N.Cl

HCID178486238

未命名化合物

PROCEDURE

实验过程

Similarly, 2-(1-methyl-5-nitro-2 -imidazolecarboximidoyl)-1-amidino-1-methylhydrazine hydrochloride (IIIC) and 2-(1-methyl-5-nitro-2-imidazolecarboximidoyl)-1-methylamidinohydrazine hydrochloride (IIID) are prepared by reacting ethyl-1-methyl-5-nitro-2-imidazolecarboximidate with 1-amino-1-methylguanidine hydrochloride and 1-amino-3-methylguanidine hydrochloride, respectively. In the like manner, 2-[1-(2-hydroxyethyl)-5-nitro-2-imidazolecarboximidoyl]-1-amidinohydrazine hydrochloride (IIIE) is prepared by reacting aminoguanidine hydrochloride with the cyclic imino ester described in Example 1.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-9c9d6efe491f4500baebe47b6d24cc01
来源数据集: uspto-grants-1976_02
DOI: 10.6084/m9.figshare.5104873.v1
专利: US03940411
来源说明: uspto-grants-1976_02

反应 SMILES

C(O[C:4]([C:6]1[N:7]([CH3:14])[C:8]([N+:11]([O-:13])=[O:12])=[CH:9][N:10]=1)=[NH:5])C.[ClH:15].[NH2:16][N:17]([CH3:21])[C:18]([NH2:20])=[NH:19].Cl.[NH2:23][NH:24][C:25]([NH:27][CH3:28])=[NH:26].Cl.OC[CH2:32][N:33]1[C:37]([N+:38]([O-:40])=[O:39])=[CH:36][N:35]=[C:34]1[C:41](NNC(=N)N)=[NH:42].C(NN)(N)=N.Cl>>[ClH:15].[CH3:14][N:7]1[C:8]([N+:11]([O-:13])=[O:12])=[CH:9][N:10]=[C:6]1[C:4]([NH:16][N:17]([C:18](=[NH:20])[NH2:19])[CH3:21])=[NH:5].[ClH:15].[CH3:32][N:33]1[C:37]([N+:38]([O-:40])=[O:39])=[CH:36][N:35]=[C:34]1[C:41]([NH:23][NH:24][C:25](=[NH:26])[NH:27][CH3:28])=[NH:42]