2-(4-Chlorophenyl)-2-(2,2,2-trichloroethyl)oxirane → 2-(3-Bromophenyl)-2-(2,2,2-trichloroethyl)oxirane

HRID 1579143Notes

Reaction equation

HRID 1579143 reaction equation
CO[C:3]1[CH:4]=[C:5]([C:9]2([CH2:12][C:13]([Cl:16])([Cl:15])[Cl:14])[CH2:11][O:10]2)[CH:6]=[CH:7][CH:8]=1.ClC1C=C(C2(CC(Cl)(Cl)Cl)CO2)C=CC=1.FC1C=C(C2(CC(Cl)(Cl)Cl)CO2)C=CC=1.ClC1C=C(C2(CC(Cl)(Cl)Cl)CO2)C=CC=1Cl.C(OC1C=C(C2(CC(Cl)(Cl)Cl)CO2)C=CC=1)C.C(OC1C=C(C2(CC(Cl)(Cl)Cl)CO2)C=CC=1)C1C=CC=CC=1.ClC1C=CC(C2(CC(Cl)(Cl)Cl)CO2)=CC=1.[Br:117]C1C=CC(C2(CC(Cl)(Cl)Cl)CO2)=CC=1>>[Br:117][C:3]1[CH:4]=[C:5]([C:9]2([CH2:12][C:13]([Cl:16])([Cl:15])[Cl:14])[CH2:11][O:10]2)[CH:6]=[CH:7][CH:8]=1

Participants

9

Reactant 8

HCID 150965752-(4-Chlorophenyl)-2-(2,2,2-trichloroethyl)oxiraneHCID 197841142-(3-Chlorophenyl)-2-(2,2,2-trichloroethyl)oxiraneHCID 203306582-(3-Ethoxyphenyl)-2-(2,2,2-trichloroethyl)oxiraneHCID 203306602-[3-(Benzyloxy)phenyl]-2-(2,2,2-trichloroethyl)oxiraneHCID 203306612-(3,4-Dichlorophenyl)-2-(2,2,2-trichloroethyl)oxiraneHCID 214402872-(3-Fluorophenyl)-2-(2,2,2-trichloroethyl)oxiraneHCID 214402922-(4-Bromophenyl)-2-(2,2,2-trichloroethyl)oxiraneHCID 214402932-(3-Methoxyphenyl)-2-(2,2,2-trichloroethyl)oxirane

Product 1

HCID 203306562-(3-Bromophenyl)-2-(2,2,2-trichloroethyl)oxirane

Procedure

2-(m-methoxyphenyl)-2-(2,2,2-trichloroethyl)oxirane; 2-(m-chlorophenyl)-2-(2,2,2-trichloroethyl)oxirane; 2-(m-fluorophenyl)-2-(2,2,2-trichloroethyl)oxirane; 2-(3,4-dichlorophenyl)-2-(2,2,2-trichloroethyl)oxirane; 2-(m-ethoxyphenyl)-2-(2,2,2-trichloroethyl)oxirane; 2-(m-(benzyloxy)phenyl)-2-(2,2,2-trichloroethyl)oxirane; 2-(p-chlorophenyl)-2-(2,2,2-trichloroethyl)oxirane; 2-(p-bromophenyl)-2-(2,2,2-trichloroethyl)oxirane; and 2-(m-bromophenyl)-2-(2,2,2-trichloroethyl)oxirane gave complete control and kill of Trichophyton mentagrophytes, Bacillus subtilis and Mycobacterium phlei.

Sources & evidence

ORD record
ord-761f3ba4582c4faf9f687b736f393291
Source dataset
uspto-grants-1976_01
Patent number
US03930835

Reaction notes

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