HCID 178429689, compound → HCID 178504632, compound

HRID 1579221Notes

Reaction equation

HRID 1579221 reaction equation
CC1C(CSC)=[N+]([O-])C2C(=CC=CC=2)[N+]=1[O-].C[C:18]1[C:27]([CH2:28][S:29]([CH3:31])=[O:30])=[N+:26]([O-:32])[C:25]2[C:20](=[CH:21][CH:22]=[CH:23][CH:24]=2)[N+:19]=1[O-:33]>>[CH3:31][S:29]([CH2:28][C:27]1[CH:18]=[N+:19]([O-:33])[C:20]2[C:25](=[CH:24][CH:23]=[CH:22][CH:21]=2)[N+:26]=1[O-:32])=[O:30]

Participants

3

Reactant 2

HCID 178429689HCID 178429689, compoundHCID 178503655HCID 178503655, compound

Product 1

HCID 178504632HCID 178504632, compound

Procedure

In like manner, 2-methyl-3-methylthiomethylquinoxaline 1,4-dioxide is converted to 2-methyl-3-methylsulfinylmethylquinoxaline 1,4-dioxide, m.p. 135°-136°C., in 13.1 percent yield.

Sources & evidence

ORD record
ord-6f3b27d88133488fafbabb33880572d1
Source dataset
uspto-grants-1976_01
Patent number
US03931174

Reaction notes

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