HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydrogen Bromide → HCID 86732881, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydrogen Bromide | HCID 260 | — |
| Reactant | Sodium Azide | HCID 33557 | — |
| Reactant | HCID 86732882 | HCID 86732882 | — |
| Solvent | Acetic Acid | HCID 176 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | HCID 86732881 | HCID 86732881 | — |
Reaction Steps
In a manner similar to that described in Example 26, treat 6β,7β-dimethanesulfonyloxy-16β-methyl-16α,17α-oxido-4-pregnene-3,20-dione with hydrogen bromide in acetic acid; treat the resulting 6β,7β-dimethanesulfonyloxy-16-methylene-17α-hydroxy-4-pregnene-3,20-dione with sodium azide in dimethylformamide to obtain 6-azido-16-methylene-17α-hydroxy-4,6-pregnadiene-3,20-dione.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03931167 |
| Source dataset | uspto-grants-1976_01 |
| ORD ID | ord-c29dcc75fa3a4a01b27db2cf184b42ad |
| Source note | uspto-grants-1976_01 |