Ammonia → 4-Carbamoylbenzoic acid

HRID 1579498Notes

Reaction equation

HRID 1579498 reaction equation
C1([O:7][C:8](=[O:18])[C:9]2[CH:17]=[CH:16][C:12]([C:13]([O-])=[O:14])=[CH:11][CH:10]=2)C=CC=CC=1.[NH3:19]>>[C:13]([NH2:19])(=[O:14])[C:12]1[CH:16]=[CH:17][C:9]([C:8]([OH:7])=[O:18])=[CH:10][CH:11]=1

Participants

3

Reactant 2

HCID 222AmmoniaHCID 22614129HCID 22614129, compound

Product 1

HCID 5060574-Carbamoylbenzoic acidYield 99%

Procedure

6.0 grams (0.025 mols) of monophenylterephthalate were brought together with 26.2 grams of liquid ammonia for reaction under the same conditions specified in Example 10. After working up the product as in all of the preceding examples, there were obtained 4.1 grams (99% of theory) of terephthalic acid monoamide.

Sources & evidence

ORD record
ord-9c7c0d27d4ca4361ae9d8b1fcf7566c3
Source dataset
uspto-grants-1976_01
Patent number
US03931210

Reaction notes

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