Methanethiol → 2-Pyrazinyl-ethyl methyl sulfide

HRID 1579689Notes

Reaction equation

HRID 1579689 reaction equation
[CH:1]([C:3]1[CH:8]=[N:7][CH:6]=[CH:5][N:4]=1)=[CH2:2].[CH3:9][SH:10].C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>>[CH3:9][S:10][CH2:2][CH2:1][C:3]1[CH:8]=[N:7][CH:6]=[CH:5][N:4]=1

Participants

4

Reactant 3

HCID 878MethanethiolHCID 7187Benzoyl PeroxideHCID 77840Vinylpyrazine

Product 1

HCID 226304002-Pyrazinyl-ethyl methyl sulfide

Procedure

h. 2-Pyrazinyl-ethyl methyl sulfide was prepared by reacting vinylpyrazine [c.f. J. Org. Chem. 27, 1363 (1962] with methylmercaptan by the action of ultra violet light and in the presence of benzoyl peroxide by the method described in Acta Chem. Scand. 8, 295 (1954). The product was identified by mass spectrometry. It has a b.p. of 57°-69°C. at 0.05 mm. Hg.

Sources & evidence

ORD record
ord-aa17b5c5d9e04dd9b7d28a96d32fc6a0
Source dataset
uspto-grants-1976_01
Patent number
US03931245

Reaction notes

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