HuagongsheHuagongshe Chemistry Print Report · For research reference only
Boron trifluoride → 4,4,8-Trimethyl-9-methylene-bicyclo[3.3.1]nonan-6-one
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Boron trifluoride | HCID 6356 | — |
| Reactant | (E)-1-(2,6,6-trimethylcyclohex-2-en-1-yl)but-2-en-1-one | HCID 5366077 | — |
| Solvent | Benzene | HCID 241 | — |
| Solvent | Diethyl Ether | HCID 3283 | — |
| Product | 4,4,8-Trimethyl-9-methylene-bicyclo[3.3.1]nonan-6-one | HCID 23338062 | — |
Reaction Steps
A solution of 2,6,6-trimethyl-1-crotonoyl-2-cyclohexene (1.0 g.) in a mixture of benzene and ether (10 ml.) was heated at ca. 80° in the presence of a catalytic amount of a saturated solution of BF3 in ether. The course of the reaction was followed by v.p.c. analysis. Three hours were usually necessary for converting the starting material into the bicyclic compound.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03931326 |
| Source dataset | uspto-grants-1976_01 |
| ORD ID | ord-59de67da72724604899c8684ee8dce92 |
| Source note | uspto-grants-1976_01 |