HuagongsheHuagongshe Chemistry Print Report · For research reference only
Nitric Acid → 2,5-Cyclohexadiene-1,4-dione, 2,3,5-trimethyl-
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Nitric Acid | HCID 944 | — |
| Reactant | 2,3,6-Trimethylphenol | HCID 17016 | — |
| Catalyst | Sodium Nitrite | HCID 23668193 | — |
| Solvent | Acetic Acid | HCID 176 | — |
| Product | 2,5-Cyclohexadiene-1,4-dione, 2,3,5-trimethyl- | HCID 70291 | 69.6% |
Reaction Steps
Also, in the process described in Japanese Pat. Publication No. 38063/70 (German Pat. OLS No. 1,814,652), 2,3,6-trimethylphenol is dissolved in acetic acid and oxidized with a dilute nitric acid using sodium nitrite as a catalyst to obtain trimethyl-p-benzoquinone in maximum yield of 69.6 percent. This process is simple and is considered to be a good one. However, the yield is a little low.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03932475 |
| Source dataset | uspto-grants-1976_01 |
| ORD ID | ord-03c3211cbb2a4164b7eb9990a21a3510 |
| Source note | uspto-grants-1976_01 |