関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Toluene | HCID 1140 | — |
| 反応物 | 1-Iodo-3-triphenylmethoxy-trans-1-octene | HCID 20144636 | — |
| 反応物 | Butyllithium | HCID 178418339 | — |
| 溶媒 | Hexane | HCID 8058 | — |
| 生成物 | HCID 178506898 | HCID 178506898 | — |
反応手順
To a solution of 4.96 g. of 1-iodo-3-triphenylmethoxy-trans-1-octene (Example 730) in 10 ml. of toluene cooled to -78°C. is added under an inert atmosphere 1 molar equivalent of n-butyllithium dissolved in hexane. The reaction mixture is allowed to warm to -40°C. and is then maintained at that temperature for 1hour to yield a hydrocarbon solution of 3-triphenylmethoxy-trans-1-octenyllithium.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US03932479 |
|---|
| 出典データセット | uspto-grants-1976_01 |
|---|
| ORD ID | ord-8707e8110a13498db0df5a106c014b3e |
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| 出典メモ | uspto-grants-1976_01 |
|---|
