HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydrochloric Acid → (3-Chloro-3-methyl-2-nitrosobutoxy)benzene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydrochloric Acid | HCID 313 | — |
| Reactant | Pentyl nitrite | HCID 10026 | — |
| Reactant | Benzene, ((3-methyl-2-butenyl)oxy)- | HCID 564931 | — |
| Solvent | Acetic Acid | HCID 176 | — |
| Product | (3-Chloro-3-methyl-2-nitrosobutoxy)benzene | HCID 21316467 | 50% |
Reaction Steps
Concentrated hydrochloric acid (7.8 ml) was added dropwise over 1 hour to a mixture of 1-(p-methoxy)phenoxy-3-methylbut-2-ene (VI; R = CH2OC6H4.OCH3, R1 = R2 = CH3) (12.0 g) and amyl nitrite (11.7 ml) in glacial acetic acid (15.6 ml) at 0°C (ice-salt bath). A white precipitate separated and this was filtered off and dried to give the nitrosochloride (V) (8.0 g, yield 50%) as colourless crystals, m.p. 137°.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03933820 |
| Source dataset | uspto-grants-1976_01 |
| ORD ID | ord-09596566a1624646b2e2b936aafcff2c |
| Source note | uspto-grants-1976_01 |